NAKANO GROUPKindai Univercity

Publications（論文）

2023

• [80] “Growth of metastable 2H-CaSi2 films on Si(111) substrates with ultrathin SiO₂ films by solid phase epitaxy”
  K. Oh-ishi, M. Kojima, T. Yoshizaki, A. Shibagaki, T. Ishibe, Y. Nakamura, H. Nakano
  Applied Physics Express 2023, 17(1), 015501.
• [79] “Efficient reducibility of layered polysilane (SiH)n for selective recovery of platinum ions from aqueous media”
  M. Ohashi, Y. Goto, H. Nakano
  New Journal of Chemistry 2023, 47(22), 10638.

2022

• [78] “Tailoring the Void Space of a Silicon Anode for High‐Capacity and Low‐Expansion Lithium Storage”
  H. Nakano, K. Oh-ishi, M. Matsubara
  Energy Technology 2022, 10(11), 2200236.
• [77] “Synthesis of Si–Ge Nanosheets and Their Dispersion of Organic Solvents with Focus on the Hansen Solubility Parameters”
  H. Nakano, D. Nakamura
  ACS Omega 2022, 7(22), 18834
• [76] “Transformation of CaSi overgrowth domains to the CaSi₂ crystal phase via vacuum annealing”
  T. Ohsuna, K. Ito, H. Nakano
  Jpn. J. Appl. Phys. 2022, 61(2) 025506.
• [75] “Giant Enhancement of Seebeck Coefficient by Deformation of Silicene Buckled Structure in Calcium-Intercalated Layered Silicene Film”
  T. Terada, Y. Uematsu, T. Ishibe, N. Naruse, K. Sato, T. Q. Nguyen, E. Kobayashi, H. Nakano, Y. Nakamura
  Adv. Mater. Interfaces 2022, 9(1), 2101752.

2021

• [74] “Thermoelectric power factor enhancement of calcium-intercalated layered silicene by introducing metastable phase”
  T. Terada, T. Ishibe, T. Katayama, K. Sato, T. Q. Nguyen, H. Nakano, Y. Nakamura
  Appl. Phys. Express 2021, 14(11), 115505.
• [73] “Suppression of thermal runaway by continuous heat generation using porous silicon covered with a thin oxide layer”
  H. Nakano, T. Inoue, T. Uyama, T. Nonaka, K. Mukai
  J. Power Sources 2021, 506, 230209.
• [72] “Polymorphic transformations of CaSi₂ and CaGe₂”
  R. Yaokawa, A. Nagoya, H. Nakano
  J. Solid State Chem. 2021, 295, 121919.

2020

• [71] “Formation of Silicon Quantum Dots Sheet on a Nonmetallic CaF₂ Surface”
  K. Ito, H. Nakano, Y. Nakamura
  Adv. Mater. Interfaces 2020, 7(23), 202001295.
• [70] “Photo-energy Transfer in sigma-pi Conjugated Polysilanes Prepared by Platinum-catalyzed Reactions of Arylacetylenes with Layered Polysilane”
  J. Ohshita, Y. Matsuzawa, T. Yagami, Y. Adachi, A. Sekiguchi, M. Ohashi, H. Nakano
  Chem. Lett. 2020, 49(10), 1174.
• [69] “Optical Properties of Silicon Nanosheets Modified with Triphenylamine and Quinoline Units: Charge and Energy Transfer from Conjugated Substituents to the Catenated Silicon Backbone”
  J. Ohshita, Y. Tanaka, K. Yamamoto, H. Kadowaki, M. Nakashima, Y. Adachi, M. Ohashi, H. Nakano
  J. Phys. Chem. C 2020, 124(31), 17347.
• [68] “Growth and fluorination of CaSi₂ thin film”
  K. Ito, T. Ohsuna, T. Suemasu, H. Nakano
  Jpn. J. Appl. Phys. 2020, 59, SFFC02.
• [67] “Solution-Processed Silicane Field-Effect Transistor: Operation Due to Stacking Defects on the Channel”
  H. Nakano, K. Ito, A. Miura, Y. Majima
  Adv. Funct. Mater. 2020, 30(15), 1908746.

2019

• [66] “Formation mechanism of Cu₂O particles using layered CaSi₂ as a reduction/oxidation mediator”
  H. Itahara, H. Nakano
  J. Am. Ceram. Soc. 2019, 102(10), 5738.
• [65] “Silicanes Modified by Conjugated Substituents for Optoelectronic Devices”
  H. Nakano, Y. Tanaka, K. Yamamoto, H. Kadowaki, M. Nakashima, T. Matsui, S. Shirai, M. Ohashi, J. Ohshita
  Adv. Opt. Mater. 2019, 7(18), 201900696.
• [64] “Hansen Solubility Parameters of Stacked Silicanes Derived from Porous Silicon”
  H. Nakano, D. Nakamura
  ACS Omega 2019, 4(7), 11838.
• [63] “Direct Chemical Synthesis of Benzyl-Modified Silicane from Calcium Disilicide”
  M. Ohashi, S. Shirai, H. Nakano
  Chem. Mater. 2019, 31(13), 4720.
• [62] “Solid-State Electrochemistry of Copper(I) Coordination Polymers Containing Tetrafluoroborate Anions”
  H. Kumagai, S. Kawata, H. Nakano
  Inorg. Chem. 2019, 58(4), 2379.

2018

• [61] “Growth of tr6-CaSi₂ thin films on Si(111) substrates”
  K. Ito, T. Suemasu, H. Nakano
  Jpn. J. Appl. Phys. 2018, 57(12), 120313.
• [60] “Liquid-Phase Exfoliation of Germanane Based on Hansen Solubility Parameters”
  D. Nakamura, H. Nakano
  Chem. Mater. 2018, 30(15) 5333.
• [59] “Crystal structures and thermodynamic stabilities of two new CaGe₂ polymorphs”
  R. Yaokawa, A. Nagoya, K. Mukai, H. Nakano
  Acta Mater. 2018, 151, 347.
• [58] “Chemical modification of group IV graphene analogs”
  H. Nakano, H. Tetsuka, M. J. S. Spencer, T. Morishita
  Sci. Technol. Adv. Mater. 2018, 19(1), 76.

2017

• [57] “Versatile Reducing Reaction Field within Layered Polysilane for Efficient One-Pot Synthesis of Metal Nanoparticles”
  M. Ohashi, R. Yaokawa, Y. Takatani, H. Nakano
  ChemNanoMat 2017, 3, 534.
• [56] “Synthesis and optical properties of two-dimensional nanosilicon compounds”
  H. Itahara, H. Nakano
  Jpn. J. Appl. Phys. 2017, 56(5), DA02.
• [55] “Determination of cation distribution in the Fe[Li_1/2Fe_3/2]O₄-LiFeTiO₄-Li[Li_1/3Ti_5/3]O₄ system: Mixed nature of solid solution and superlattice”
  K. Mukai, Y. Kato, H. Nakano
  J. Solid State Chem. 2017, 247, 67.
• [52] “Improving Powder Magnetic Core Properties via Application of Thin, Insulating Silica-Nanosheet Layers on Iron Powder Particles”
  T. Ishizaki, H. Nakano, S. Tajima, N. Takahashi
  Nanomaterials 2017, 7, 1.

2016

• [51] “Soft chemical synthesis of silicon nanosheets and their applications”
  H. Nakano, T. Ikuno
  Appl. Phys. Rev. 2016, 3, 040803.
• [50] “Multilayer Germanenes Formed in Zintl-Phase CaGe₂ by Fluoride Diffusion”
  R. Yaokawa, T. Ohsuna, Y. Hayasaka, H. Nakano
  ChemistrySelect 2016, 1(17), 5579.
• [49] “Easy Access to Martin's Hypervalent Sulfur Anions toward an Electrode Material for Organic Rechargeable Batteries”
  Y. Imada, T. Kukita, H. Nakano, Y. Yamamoto
  Bull. Chem. Soc. Japan 2016, 89(5), 546.
• [48] “Preparation and Photocurrent Generation of Silicon Nanosheets with Aromatic Substituents on the Surface”
  J. Ohshita, K. Yamamoto, D. Tanaka, M. Nakashima, Y. Kunugi, M. Ohashi, H. Nakano
  J. Phys. Chem. C 2016, 120(20), 10991.
• [47] “Monolayer-to-bilayer transformation of silicenes and their structural analysis”
  R. Yaokawa, T. Ohsuna, T. Morishita, Y. Hayasaka, M. J. S. Spencer, H. Nakano
  Nat. Commun. 2016, 7, 10657.
• [46] “Isolation of Hypervalent Group-16 Radicals and Their Application in Organic-Radical Batteries”
  Y. Imada, H. Nakano, K. Furukawa, R. Kishi, M. Nakano, H. Maruyama, M. Nakamoto, A. Sekiguchi, M. Ogawa, T. Ohta, Y. Yamamoto
  J. Am. Chem. Soc. 2016, 138(2), 479.

2015

• [45] “Improving battery safety by reducing the formation of Li dendrites with the use of amorphous silicon polymer anodes”
  H. Maruyama, H. Nakano, M. Ogawa, M. Nakamoto, T. Ohta, A. Sekiguchi
  Sci. Rep. 2015, 5, 13219.
• [44] “Characteristics of layered polysilane and its application to lithium ion battery anodes”
  Y. Kumai, H. Nakano
  Jpn. J. Appl. Phys. 2015, 54(3), 035201.
• [43] “Direct Observation of Dirac Cone in Multilayer Silicene Intercalation Compound CaSi₂”
  E. Noguchi, K. Sugawara, R. Yaokawa, T. Hitosugi, H. Nakano, T. Takahashi
  Adv. Mater. 2015, 27(5), 856.
• [42] “Surface Modification of Layered Polysilane with n-Alkylamines, alpha,omega-Diaminoalkanes, and omega-Aminocarboxylic Acids”
  H. Okamoto, Y. Sugiyama, K. Nakanishi, T. Ohta, T. Mitsuoka, H. Nakano
  Chem. Mater. 2015, 27(4), 1292.

2014

• [41] “Growth of CaSi₂ single-phase polycrystalline ingots using the phase relationship between CaSi₂ and associated phases”
  R. Yaokawa, H. Nakano, M. Ohashi
  Acta Mater. 2014, 81, 41.
• [40] “Synthesis and modification of two-dimensional crystalline silicon nanosheets”
  H. Nakano
  J. Ceram. Soc. Jpn. 2014, 122(1429), 748.
• [39] “Mechanochemical lithiation of layered polysilane”
  M. Ohashi, H. Nakano, T. Morishita, M. J. S. Spencer, Y. Ikemoto, C. Yogi, T. Ohta
  Chem. Commun. 2014, 50(68), 9761.
• [38] “Factors Affecting the Volumetric Energy Density of Lithium-Ion Battery Materials: Particle Density Measurements and Cross-Sectional Observations of Layered LiCo_1-xNi_xO₂ with 0 ≦ x ≦ 1”
  K. Mukai, H. Nakano
  ACS Appl. Mater. Interfaces 2014, 6(13), 10583.
• [37] “Understanding the Zero-Strain Lithium Insertion Scheme of Li[Li_1/3Ti_5/3]O₄: Structural Changes at Atomic Scale Clarified by Raman Spectroscopy”
  K. Mukai, Y. Kato, H. Nakano
  J. Phys. Chem. C 2014, 118(6), 2992.
• [36] “High-Power Electrochemical Energy Storage System Employing Stable Radical Pseudocapacitors”
  H. Maruyama, H. Nakano, M. Nakamoto, A. Sekiguchi
  Angew. Chem., Int. Ed. 2014, 53(5), 1324.
• [35] “Anion secondary batteries utilizing a reversible BF₄ insertion/extraction two-dimensional Si material”
  H. Nakano, Y. Sugiyama, T. Morishita, M. J. S. Spencer, I. K. Snook, Y. Kumai, H. Okamoto
  J. Mater. Chem. A 2014, 2(20), 7588.

2013

• [34] “Interactions between stacked layers of phenyl-modified silicene”
  M. J. S. Spencer, M. R. Bassett, T. Morishita, I. K. Snook, H. Nakano
  New J. Phys. 2013, 15, 125018

2012

• [33] “Preparation of Alkyl-Modified Silicon Nanosheets by Hydrosilylation of Layered Polysilane (Si₆H₆)”
  H. iNakano, M. Nakano, K. Nakanishi, D. Tanaka, Y. Sugiyama, T. Ikuno, H. Okamoto, iT. Ohta
  J. iAm. Chem. Soc 2012, 134(12), 5452.

2010

• [32] “Synthesis and Modification of Silicon Nanosheets and Other Silicon Nanomaterials”
  H. Okamoto, Y. Sugiyama, H. Nakano
  Chem.-A Eur. J. 2011, 17(36), 9864.
• [31] “Electron transport properties of Si nanosheets: Transition from direct tunneling to Fowler-Nordheim tunneling”
  T. Ikuno, H. Okamoto, Y. Sugiyama, H. Nakano, F. Yamada, I. Kamiya
  Appl. Phys. Lett. 2011, 99, 023107.
• [30] “Characteristics and structural change of layered polysilane (Si₆H₆) anode for lithium ion batteries”
  Y. Kumai, S. Shirai, E. Sudo, J. Seki, H. Okamoto, Y. Sugiyama, H. Nakano
  J. Power Sources 2011, 196(3), 1503.
• [29] “Si-C composite anode of layered polysilane (Si₆H₆) and sucrose for lithium ion rechargeable batteries
  Y. Kumai, H. Kadoura, E. Sudo, M. Iwaki, H. Okamoto, Y. Sugiyama, H. Nakano
  J. Mater. Sci. 2011, 21(32), 11941.
• [28] “The electronic and structural properties of novel organomodified Si nanosheets”
  M. J. S. Spencer, T. Morishita, M. Mikami, I. K. Snook, Y. Sugiyama, H. Nakano
  Phys. Chem. Chem. Phys. 2011, 13(34), 15418.

2010

• [27] “Synthesis of Siloxene Derivatives with Organic Groups”
  Y. Sugiyama, H. Okamoto, H. Nakano
  Chem. Lett. 2010, 39(9), 938.
• [26] “Synthesis and Optical Properties of Monolayer Organosilicon Nanosheets”
  Y. Sugiyama, H. Okamoto, T. Mitsuoka, T. Morikawa, K. Nakanishi, T. Ohta, H. Nakano
  J. Am. Chem. Soc. 2010, 132(17), 5946.
• [25] “Silicon Nanosheets and Their Self-Assembled Regular Stacking Structure”
  H. Okamoto, Y. Kumai, Y. Sugiyama, T. Mitsuoka, K. Nakanishi, T. Ohta, H. Nozaki, S. Yamaguchi, S. Shirai, H. Nakano
  J. Am. Chem. Soc. 2010, 132(8), 2710.

2010年以前はresearchmap参照

Reviews and Book Chapters
（解説記事と著書）

• [13] シリコンおよびゲルマニウム二次元物質の液相化学
  中野秀之
  ケイ素化学協会誌 2023, 40, pp. 5−11.
• [12] ケイ素及びゲルマニウム二次元化合物の合成と物性
  中野秀之
  ポストグラフェン材料の創製と用途開発最前線 : 二次元ナノシートの物性評価、構造解析、合成、成膜プロセス技術、応用展開 2020, pp. 149−157（エヌ・ティー・エス出版）.
• [11] 特集「広がる2次元材料の世界」“ケイ素とゲルマニウム2次元化合物の化学”
  中野秀之
  化学と工業 2019, 72(4), 332.
• [10] 層状結晶CaX₂(X=Si, Ge)中に成長させた多層シリセンおよびゲルマネン
  中野秀之、八百川律子
  セラミックス 2018, 53(5), 328−330.
• [9] Two-dimensional silicon nanosheets
  H. Nakano
  Silicon Nanomaterials Sourcebook, Two-Volume Set (Series in Materials Science and Engineering) 2017, pp. 77−94 (CRC Press).
• [8] ケイ素材料の二次電池への応用
  関口章、中野秀之
  月刊ファインケミカル 2017, 46(8), 5−16.
• [7] シリコンのエキゾチックな形態
  生野孝、中野秀之
  パリティ 2017, 32, 8.
• [6] Soft Chemical Synthesis of Functionalized Silicene
  H. Nakano
  Silicene Structure, Properties and Applications 2016, pp. 85−106 (Springer).
• [5] グラフェンのシリコン版：シリセンの化学と応用
  中野秀之
  ケイ素化学協会誌 2015, 32, 5−11.
• [4] シリコンナノシートの作製と応用
  大橋雅卓、中野秀之
  Electrochemistry 2015, 83(8), 648−652.
• [3] シリコンナノシートの合成技術と電池特性・光学特性
  板原浩、今川晴雄、大橋雅卓、中野秀之
  触媒 2015, 57(6), 348−354.
• [2] ２次元シリコンナノ材料の創製と機能賦与
  大橋雅卓、中野秀之
  Ceramic Data Book 2005, 42. 61−64.
• [1] CaSi2と関連物質
  中野秀之
  無機ナノシートの科学と応用 2005, pp.112−118 (シーエムシー出版).

Invited talk（招待講演）

• [20] 2021. 1. 科学技術イノベーションを創成する先進システムナノ技術
  “シリコンを原子層まで薄くしたシリセンの創製”
• [19] 2020. 11. 超分子研究会・精密ネットワークポリマー研究会第４回合同講座
  “ケイ素、ゲルマニウムを基軸とする二次元物質の創製と応用”
• [18] 2019. 4. 日本表面真空学会関東支部大会
  “二層シリセン及びゲルマネンの成長と構造解析”
• [17] 2019. 1. ポストグラフェン材料のデバイス開発研究会
  “シリコンおよびゲルマニウム二次元物質のソフト化学合成と物性”
• [16] 2017. 5. 第44回触媒化学融合研究センター講演会
  “SiおよびGeナノシートの創製と応用”
• [15] 2016. 7. Asia-Pacific Conference on Semiconducting Silicides and Related Materials (APAC-SILICIDE 2016)
  “Two-Dimensional Silicon Nanosheets; Controllable Exfoliation and Exploration of Functionality”
• [14] 2016. 2. 広島大学環境共生スマート材料研究拠点ケイ素材料の新展開
  “硬いシリコンと柔らかいシリコン”
• [13] 2016. 2. 平成27年度関西支部セミナーナノシートの最前線
  “シリコンを一原子層だけ剥離して機能化する技術”
• [12] 2016. 2. Kumamoto Symposium on Two Dimensional Nanomaterials
  “Chemical Modification of Silicon Nanosheet”
• [11] 2016. 2. 東京工業大学応用セラミックス研究所第7回材料構造講演会
  “劈開できないシリコンから二次元シリコン物質を創る技術”
• [10] 2015. 6. 高分子学会第34回無機高分子シンポジウム
  “柔軟な二次元シリコンの電極材料への応用”
• [9] 2014. 12. 平成26年度日本セラミックス協会東海支部学術研究発表会
  “二次元シリコンナノ結晶材料の創製、機能設計、応用展開”
• [8] 2014. 9. 日本セラミックス協会第27回秋季シンポジウム
  “グラフェンのシリコン版:機能性シリコンナノシートの創製”
• [7] 2014. 3. 日本セラミックス協会2014年年会
  “シリコンナノシートの創製と機能賦与に関する研究”
• [6] 2013. 5. 45th Silicon Symposium
  “Silicon Nanosheets Derived from Layered Silicon Compounds and their Properties”
• [5] 2012. 9. International Symposium Functional Materials Based on Silicon-Oxygen Systems
  “Synthesis of Functional Silicon Nanosheets and Their Properties”
• [4] 2012. 9. 日本物理学会2012年秋季大会
  “シリコン原子膜の合成と機能”
• [3] 2011. 11. 第15回ケイ素化学協会シンポジウム
  “シリコンナノシート、および有機化シリコンナノシートの合成と物性”
• [2] 2010. 10. 3rd International Congress on Ceramics（ICC3)
  “Organo Silicon Nanosheets Derived Layered Silicon Compounds”
• [1] 2010. 10. 立命館大学SRセンター研究成果報告会
  “新機能性材料シリコンナノシートの合成､物性､評価”

Patent（特許）

• 出願特許　127件、登録特許　56件